A review paper on rhodium-catalyzed carbon-hydrogen bond activation published by Dalian Chemical
Recently, researcher and member Li Xingwei of the Metal Synthesis and Molecular Activation Research Group, Dalian Institute of Chemical Physics, Chinese Academy of Sciences was invited to publish in the Chem. Soc. Rev. the form of trivalent rhodium (Rh (III)) catalyzed CH bond activation and critical review Review paper on oxidative functionalization.
Metal-catalyzed CH bond activation and functionalization is one of the effective methods to construct CC, CO, CN and other chemical bonds. This method has the advantages of simplicity and high atom economy. Previous research in this area has focused on the field of palladium catalysis. Since 2007, trivalent rhodium complex as a new metal catalyst has been applied to the catalytic activation of CH bonds. Under the action of Rh (III), the oxidative coupling of CH bonds with unsaturated molecules such as olefins, alkynes, aldehydes, etc. is achieved, thereby achieving the formation of CC, CN, CO bonds. Rh (III) catalysis has the advantages of low catalyst dosage, high stability, mild conditions, high selectivity, and a wide range of substrates. It has received extensive attention and rapid development in the fields of basic research and organic total synthesis.
Dahua Institute of Metal Synthesis and Molecular Activation Research Group has been engaged in research in this field since 2010 and has accumulated more research results. The review covers 138 related literatures, including 12 research papers in this group, which has certain guiding significance for the further development and design of metal-catalyzed CH bond activation and the construction of complex organic molecules.
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